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N- and C-terminal Protein Sequencing Using in-source-decay (ISD) MALDI MS

Type: Application

Application Note

Expression Proteomics

Number: Technology

2000902

MALDI-TOF

Year Products

2010

  Author
 

Ejvind Mortz, Thanh Ha Nguyen, and Janne Crawford. Alphalyse A/S, Unsbjergvej 4, Odense, Denmark.

Email correspondence: mortz @ alphalyse.com

Alphalyse A/S

Unsbjergvej 4

Dk-5220 Odense sø, Denmark

Tel +45 6310 6500

  Reference
 

Alphalyse Application Note # 2000902

 

Abstract

 

Analytical characterization of purified proteins, in particular recombinant proteins for drug discovery and development, requires confirmation of the full length protein sequence. Here we present a powerful mass spectrometry method (MALDI ISD) that provides partial sequence information of the intact protein with up to 20-50 amino acid residues from both the N-terminal and C-terminal in one single analysis. The analysis can thus confirm expression and purification of the full length protein sequence, and detect unexpected truncations and modifications of the termini. The MALDI ISD analysis can also be applied to N-terminally blocked and PEGylated proteins. Alphalyse provides protein analysis services and here we present results obtained on a variety of proteins.

 

 

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